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Hydrogen bonds can occur between molecules (intermolecularly), or within different parts of a single molecule (intramolecularly).
These protein factors act in trans (i.e., intermolecularly).
The methyl groups interchange readily intramolecularly and intermolecularly.
The Mannich reaction can proceed both intermolecularly and intramolecularly:
Carbene insertions into carbon-hydrogen bonds can also occur intermolecularly:
Horseshoe crab TGase, however, does not cross-link coagulins intermolecularly.
A number of tandem reactions, in which the intermediate alkylpalladium complex is intercepted either intra- or intermolecularly before β-hydride elimination, have also been developed.
This is unlike pressure, which only acts on a surface of an object, not its interior - pressure-type forces must be transferred to the interior of a body intermolecularly.
Then the excess energy of the excitation is transferred interatomically (intermolecularly) to remove an outer-valence electron from another cluster subunit with an ionization threshold lower than the excitation energy.
The exact reaction mechanism is not completely clear, but evidence indicates that the rearrangement occurs intermolecularly and that the migrating group is transferred to a polyalkylbenzene, not to the sulfonic acid (sulfonation only takes place after migration).
Aryl iodides were found to be suitable substrates for the intramolecular variant of this reaction, and importantly, could be coupled intermolecularly only if dioxane was used in place of toluene as a solvent, albeit with modest yields.